Efficient synthesis of akolactone A via Pd-catalyzed carbonylation.
نویسندگان
چکیده
The first synthesis of (+)- and (-)-akolactone A is described by using Pd-catalyzed carbonylation. A comparison of the optical rotation of both enantiomers of akolactone A and the natural compound suggests that the absolute configuration at the 4-position of akolactone A is R.
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ورودعنوان ژورنال:
- Bioscience, biotechnology, and biochemistry
دوره 67 12 شماره
صفحات -
تاریخ انتشار 2003